湖南师范大学化学化工学院

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梁云

发布日期:2019年11月27日 09:11浏览次数:


梁云

性 别:男

学历:博士

职称:教授

其他:博士生导师


主要教育和工作经历:

2007-现今 湖南师范大学硕士生导师、教授

2009-2011 北京大学博士后

2005-2007 获湖南师范大学理学博士学位

2002-2005 获湖南师范大学工学硕士学位

1990-1994 获湖南师范大学化学教育学士学位

研究领域和兴趣:

1. 基于无机硫源合成硫杂环化合物的研究

2. 过渡金属催化的偶联反应及串联反应研究

3. 基于邻三甲基硅芳基磺酸酯为芳炔前体的应用研究

4. 多反应位点化合物的交叉偶联反应研究

科学研究基金项目

1.

教育部科学技术项目:基于芳炔与羧酸酯的反应及其在有机合成中应用研究

2.

3.

国家自然科学基金面上项目:基于芳炔与碘叶立德反应及其应用的研究

4.

5.

湖南省自然科学基金重点项目:基于芳炔与羧酸酯的反应及其在有机合成中应用研究

6.

7.

教育厅科学技术项目:基于芳炔与羧酸酯的反应及其在有机合成中应用研究

8.

9.

教育部博士点新教师基金:基于邻三甲基硅芳基三氟磺酸酯为芳炔的前体与碘叶立德反应的研究

10.

11.

湖南师范大学青年优秀人才基金:基于芳炔与碘叶立德反应及其应用的研究

12.

13.

中国博士后科学基金:基于多卤代丁二烯型化合物交叉偶联串联反应研究

14.

15.

湖南省教育厅优秀青年基金:基于邻三甲基硅芳基三氟磺酸酯为芳炔的前体与碘叶立德反应的研究

16.

17.

北京分子科学国家实验室:基于1,1-偕二卤-1,4-共轭二卤化合物多反应位点的交叉偶联-串联反应研究

18.

发表论文

1. Dang,P.; Zeng, W.; Liang, Y.* Copper-CatalyzedThree-Component Synthesis ofBenzothiazolethiones from oIodoanilines, Isocyanide, and Potassium Sulfide, Org. Lett. 2015, 17, 34-37.

2. Yang, Y.;Huang, H.; Liu, W.; Liang, Y.* DualRole of Alkynyl Bromides in One-Step Synthesis ofBromo-Substituted AlkynylSulfides, Synth. Commun. 2015, 45, 86-93.

3. Zhang, X.;Zeng, W.; Yang, Y.; Huang, H.; Liang, Y.*, Copper-catalyzed double C−S bonds formation via differentpaths: synthesisof benzothiazoles from N-benzyl-2-iodoaniline and potassiumsulfide, Org. Lett. 2014, 16, 876-879.

4. Yang, Y.;Zhang, X.; Zeng, W.; Huang, H.; Liang, Y.*, Copper catalyzed three-component synthesis ofbenzothiazolonesfrom o-iodoanilines, DMF, and potassium sulfide, RSC Adv. 2014, 4, 6090-6093.

5. Yang,Y.;Huang,H.; Wu, L.; liang, Y.* Palladium-catalyzedannulation of benzynes withN-substituted-N-(2-halophenyl)formamides: synthesisof phenanthridinones, Org. Biomol. Chem. 2014, 12, 5351-5355.

6. Zeng, W.;Dang, P.; Zhang, X.; Liang Y. *; Peng, C. Copper-catalyzedsynthesis of2-aminobenzothiazoles from carbodiimide and sodium hydrosulfide, RSC Adv.2014, 4, 31003-31006.

7. Wu, L.;Huang, H.; Liang, Y.*; Cheng, Pi. Regio- andStereoselective Synthesis of 2Amino-dienes via Decarboxylative Amination of 4(Ethoxycarbonyl)-2,3-allenols by TsNCO, J. Org. Chem. 2014, 79, 11264-11269.

8. Huang, H.;Yang, Y.; Zhang, X.; Zeng, W. Liang, Y.*,Transition-metal-free approach to synthesis of indolinesfromN-(ortho-chloromethyl)aryl amides and iodonium ylides, Tetrahedron Lett. 2013, 54, 6049-6052.

9. Yang, Y.;Huang, H.; Zhang, X.; Zeng, W.; Liang, Y.*,Synthesis of2-alkynyltetrahydrofuran derivatives fromtetrahydrofuran and alkynyl bromides,Synthesis 2013, 3137-3146.

10. Zhang, X.; Zeng, W.; Yang, Y.;Huang, H.; Liang, Y.*,Transition-metal-freemethod for the synthesis of benzo[b]thiophenesfrom o-halovinylbenzenesand K2S via direct SNAr-typereaction, cyclization, anddehydrogenation process, Synlett. 2013,24, 1687-1692.

11. Liang, Y.; Geng, W.; Wei, J.; Xi, Z.*Palladium-Catalyzed Intermolecular Coupling of 2-Silylaryl Bromides withAlkynes: Synthesis of Benzosiloles and Heteroarene-Fused Silolesby CatalyticCleavage of the C(sp3)-Si Bond, Angew. Chem. Int. Ed. 2012,51, 1934.

12. Yang, Y.; Zhang, X.; Liang, Y.*Copper-catalyzed coupling of 1,2-dibromo-1-styrenes withsulfonamidesfor the preparation of ynamides, Tetrahedron Lett.2012, 53, 6557-6560.

13. Zhang, X.; Yang, Y.; Liang, Y.*Palladium-catalyzed double N-arylation to synthesizemultisubstituted dibenzoazepine derivatives, Tetrahedron Lett. 2012, 53, 6406-6408.

14. 张晓昀,杨源,梁云*,利用无机硫源构建含硫杂环化合物的研究,第八届有机化学学术会议论文集,66页,2013.10.17-20,重庆,邀请报告。

15. Liang, Y.; Geng, W.; Wei,J.; Ouyang, K.; Xi, Z.* Palladium-catalyzedsilyl C(sp3)-H bondactivation, Org. Biomol. Chem.2012, 10,1537-1542.

16. Liang, Y.; Zhang, S,Xi, Z.* Palladium-Catalyzed Synthesis of Benzosilolo[2,3-b]indoles via Cleavage of a C(sp3)-SiBond and Consequent Intramolecular C(sp2)-Si Coupling J, Am,Chem, Soc. 2011, 133, 9204.

17. Liang, Y.; Meng, T.; Zhang, H.; Xi, Z.*Palladium-catalyzed, one-pot, three-component approach to a-alkynylindoles from o-bromo-(2,2-dibromovinyl)benzenes,terminal alkynes and arylamines, Synlett. 2011, 911.

18. Pi, S.-F.; Yang, X.-H.; Huang, X.-C.; Liang, Y.*; Yang, G.-N.; Zhang, X.-H.; Li,J.-H.* Palladium-CatalyzedCyclocarbonylation of Arynes with Methyl Allyl Carbonates: Selective Synthesisof 1H-Inden-1-ones, J.Org. Chem, 2010, 75, 3484.

19. Li, R.-J.; Pi, S.-F.; Liang, Y.*; Wang, Z.-Q.; Song, R.-J.;Chen, G.-X.; Li, J.-H.* Palladium-catalyzedannulations of arynes with 2-(2-iodophenoxy)-1-substituted ethanones Chem.Commun., 2010, 8183.

20. Liu, Y.-L.; Liang, Y.;* Pi, S.-F.; Li, J.-H.*, Selective Synthesis of o-Acylbenzylphosphonatesby Insertion Reactions of Arynes into β-Ketophosphonates, J.Org. Chem, 2009, 74, 5691.

21. Pi, S.-F.; Tang, B.-X.; Yin, D.-L.; Li, J.-H.*; Liu, Y.-L.; Liang,Y.*, Palladium-Catalyzed Decarboxylative Coupling of AllylicAlkynoates with Arynes, Org. Lett., 2009, 11,2309.

22. Liu, Y.-L.; Liang, Y.;* Pi, S.-F.; Huang, X.-C.; Li,J.-H.*, Palladium-Catalyzed Cocyclotrimerization of Allenes with Arynes:Selective Synthesis of Phenanthrenes, J. Org. Chem, 2009, 74,3199.

23. Huang, X.-C.; Wang, F.; Liang, Y.;* Li, J.-H.*,Halopalladation/Decarboxylation/Carbon-Carbon Forming Domino Process: Synthesisof 5-Halo-6-substituted Benzo[b]naphtho[2,1-d]furans, Org.Lett., 2009, 11, 1139.

24. Huang, X.-C.; Liu, Y.-L.; Liang, Y.;* Pi, S.-F.; Wang, F.; Li, J.-H.*,Cycloaddition of Arynes with Iodonium Ylides: A Mild and General Route for theSynthesis of Benzofuran Derivatives, Org. Lett. 2008, 10,1525.

25. Xie, Y.-X.; Wang, J.; Li, J.-H.*; Liang, Y.*, Reusable and Ligand-Free Palladium-CatalyzedSuzuki-Miyaura Cross-Couplings of Aryl Halides with Arylboronic Acids in Tetra-n-butylammonium Bromide, ChineseJournal of Chemistry, 2008, 26, 2261.

26. Liang,Y.; Tao, L.-M.;Zhang, Y.-H.; Li, J.-H.*, Palladium-Catalyzed Cross-Coupling Reactions of1,2-Diiodoalkenes with Terminal Alkynes: Selective Synthesis of UnsymmetricalButa-1,3-diynes and 2-Ethynylbenzofurans, Synthesis. 2008,3988.

27. Liang,Y.; Xie, Y.-X.; Li, J.-H.* Cy2NHHX-Promoted Cyclizations ofo-(1-Alkynyl)benzoates and (Z)-2-Alken-4-ynoate with Copper Halides toSynthesize Isocoumarins and a-Pyrone, Synthesis. 2007, 3,400.

28. Liang,Y.; Tang, S.; Zhang, X.-D.; Mao, L.-Q.; Xie, Y.-X.; Li, J.-H.* Noveland Selective Palladium-Catalyzed Annulations of 2-Alkynylphenols To Form2-Substituted 3-Halobenzo[b]furans, Org.Lett. 2006, 8, 3017.

29. Liang,Y.; Xie, Y.-X.; Li, J.-H.* General and Modified Palladium-CatalyzedSonogashira Cross-Coupling Reaction under Copper-, Amine- and Solvent-FreeConditions, J. Org. Chem. 2006, 71,379.

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