化学化工学院 化学化工学院


 


联系信息:

 

jxsong@hunnu.edu.cn


基本信息

宋建新,科研副院长,二级教授,博士生导师,湖南省“芙蓉学者奖励计划”特聘教授,湖南省普通高校学科带头人,湖南省科技创新团队负责人,湖南省普通高校材料类专业教学指导委员会副秘书长(2023-2028)。学习经历: 1996、1999年先后在湖南师范大学获得学士、硕士学位、2003年在湖南大学获得博士学位,2002年博士期间曾留学美国。工作经历: 2003-2005,湖南大学,讲师;2005-2009,湖南大学,副教授;2004-2007,吉首大学,特聘教授(受教育厅指派兼任)。2006-2008,京都大学,博士后;2008-2010,京都大学,研究员;2011年7月至今,湖南师范大学,教授。

研究方向

1.卟啉纳米分子、卟啉类似物的设计、合成与性能研究。

2.新颖杂环共轭体系的设计、合成与性能研究。

3.光电转换材料、抗癌药物的合成与筛选。

 

主持项目

 

    1.N错位smaragdyrin的设计、合成与性能研究,50万,国家自然科学基金项目,2025.01-2028.12

2.大环功能分子的制备与性能研究,200万,湖南省科技厅, 2021.09-2024.09

3.Smaragdyrin 稠合体的设计、合成与性能研究,63万,国家自然科学基金项目 2021.01-2024.12

4.耳坠型卟啉的结构修饰与性能研究,64万,国家自然科学基金项目,2018.01-2021.12

5.卟啉纳米环阵列的设计、合成与性能研究,80万,国家自然科学基金项目,2012.01-2016.12


代表论文(2011年7月入职以来)

1. Y. Rao, J. Lee, J. Chen, L. Xu, M. Zhou, B. Yin, J. Kim,* A. Osuka,* J. Song,* 5,18-Dimesitylorangarin: A Stable Antiaromatic [20]Pentaphyrin(1.0.1.0.0) Displaying Remarkable Oxidative Self-Coupling Reactions, Angew. Chem. Int. Ed., 2024, 63, e202409655


2. Y. Liu, T. Tanaka, D. Shimizu, Y. Rao, L. Xu, B. Yin, M. Zhou, J. Song,* A. Osuka, Fused Aromatic and Antiaromatic Smaragdyrin Dimers, Angew. Chem. Int. Ed., 2024, 63, e202408478

3. J. Chen, L. Liu, Y. Rao,* L. Xu, M. Zhou, B. Yin, S. Shimizu, D. Shimizu, A. Osuka,* J. Song,* [22]Pentaphyrins(2.0.1.1.0) Displaying N-Fusion, Pyrrole Rearrangement, and Dimerization Reactions Upon Oxidation and Metalation, Angew. Chem. Int. Ed., 2024, 63, e202407340

4. K. Wang, S. Ito, S. Ren, D. Shimizu, N. Fukui, R. Kishi, Q. Liu,* A. Osuka, J. Song,* H. Shinokubo,* A Triply Linked Porphyrin-Norcorrole Hybrid with Singlet Diradical Character, Angew. Chem. Int. Ed., 2024, 63, e202401233

5. L. Zhi, L. Liu, M. Zhou,* L. Liu, B. Xiao, L. Xu, Y. Rao, B. Yin, J. Song,* A. Osuka, Synthesis of Pyrrole-Sharing Fused Porphyrinoid Hybrids by Post-fabrication of Ni Porphyrins, Angew. Chem. Int. Ed., 2024, 63, e202319005

6. F. Luo, L. Liu, H. Wu, L. Xu, Y. Rao, M. Zhou, A. Osuka, J. Song,* Doubly N-Confused and Ring-Contracted [24]Hexaphyrin Pd-Complexes as Stable Antiaromatic N-confused Expanded Porphyrins, Nat. Commun., 2023, 14, 5028

7. M. Ye, F. Deng, L. Xu, Y. Rao, B. Yin, M. Zhou, R. Kurosaki, N. Aratani, A. Osuka, J. Song,* A Quadruply Bridged Non-offest Face-to-Face Poprhyrin Dimer and Cross-Shaped Pentameric Porphyrin Tapes Based on 2,7,12,17-tetrakis (pinacolatoboryl) NiII Porphyrin, Angew. Chem. Int. Ed., 2023, 62, e202300260

8. Y. Wu, T. Zhao, J. Rong, Y. Rao, M. Zhou, B. Yin, X. Ni, A. Osuka, L. Xu,* J. Song,* Low-valent Zirconocene-Mediated Synthesis of Porphyrin(2.1.2.1)s and Its Extension to synthesis of a Porphyrin(2.1.2.1) Nanobarrel, Angew. Chem. Int. Ed., 2022, 61, e202201327

9. Y. Liu, D. Xie, Y. Rao, L. Xu, M. Zhou, A. Osuka, J. Song,* Fused Hybrids of a [22]Smaragdyrin BF2 Complex with a NiII Porphyrin, Angew. Chem. Int. Ed., 2022, 61, e202206601

10. Y. Rao, L. Xu, M. Zhou, B. Yin, A. Osuka,* J. Song,* Expanded Azaporphyrin Consisting of Multiple BODIPY Unites: Golbal Aromaticity and High Affinities Towards Alkali Metal Ions, Angew. Chem. Int. Ed., 2022, 61, e202206899

11. H. Shu, M. Guo, M. Wang, M. Zhou,* B. Zhou, L. Xu, Y. Rao, B. Yin, A. Osuka, J. Song,* Efficent Synthesis of Multiply Seven-Membered- Ring Fused Porphyrins by Rhodium-Catalyzed [5+2] Annulation, Angew. Chem. Int. Ed., 2022, 61, e202209594

12. L. Liu, J. Kim, L. Xu, Y. Rao, M. Zhou, B. Yin, J. Oh, D. Kim,* A. Osuka,* J. Song,* Synthesis of Subporphyrin Free Bases, Angew. Chem. Int. Ed., 2022, 61, e202214342

13. K. Wang, P. Liu, F. Zhang, L. Xu, M. Zhou, A. Nakai, K. Kato, K. Furukawa, T. Tanaka, A. Osuka, J. Song,* A Robust Porphyrin-Stabilized Triplet Carbon Diradical, Angew. Chem. Int. Ed., 2021, 60, 7002

14.L. Liu, Z. Hu, F.Zhang, Y. Liu, L. Xu, M. Zhou, T. Tanaka, A. Osuka, J. Song*, Benzene- and pyridine-incorporated octaphyrins with different coordination modes toward two PdII centers, Nat. Commun., 2020, 11, 6206

15. Y. Rao, W. Zhou, L. Xu, M. Zhou, B Yin, T. Tanaka, A. Osuka, J. Song*, Singly and Doubly Neo-Confused Smaragdyrins, J. Am. Chem. Soc., 2019, 141, 18836

16. L. Wu, F. Li, Y. Rao, B. Wen, L. Xu, M. Zhou, T. Tanaka, A. Osuka, J. Song*, Synthesis, Structures, and Near-IR Absorption of Heterole-Fused Earring Porphyrins, Angew. Chem. Int. Ed., 2019, 58, 8124.

17. D. Xie, Y. Liu, Y. Rao, G. Kim, M. Zhou, D. Yu, L. Xu, B. Yin, S. Liu, T. Tanaka, N. Aratani, A. Osuka, Q. Liu, D. Kim,* and J. Song* meso-Triaryl-Substituted Smaragdyrins: Facile Aromaticity Switching , J. Am. Chem. Soc., 2018, 140, 16553.

18. L. Xu, B. Wen, G. Kim, T. Kim, F. Chen, M. Zhou, L. Xu, T. Tanaka, B. Yin, A. Osuka, D. Kim* and J. Song,* Strategic Construction of Directly Linked Porphyrin-BODIPY Hybrids, Angew. Chem. Int. Ed., 2017, 56, 12322.

19. Y. Rao, T. Kim, K. H. Park, F. Peng, L. Liu, Y. Liu, B. Wen, S. Liu, S. R. Kirk, L. Wu, B. Chen, M. Ma, M. Zhou, B. Yin, Y. Zhang, D. Kim,* and J. Song*, π-extended earring porphyrins with multiple cavities and near infrared absorptions, Angew. Chem. Int. Ed., 2016, 55, 6438.

20. H. Cai, K. Fujimoto, J. M. Lim, C. Wang, W. Huang, Y. Rao, S. Zhang, H. Shi, B. Yin, B. Chen, M. Ma, J. Song,* D. Kim* and A. Osuka*, synthesis of β-to-β direct linked porphyrin arrays with large electronic interactions: branched and cyclic oligomers, Angew. Chem. Int. Ed., 2014, 53, 11088.



编著

1. Xu L., Wang K., Song J.*, (2019) Constructions and Properties of Covalent Bonds Linked Porphyrin Arrays. In: Liu Y., Chen Y., Zhang HY. (eds)Handbook of Macrocyclic Supramolecular Assembly. Springer, Singapore.

Doi: 10.1007/978-981,-13-1744-6_37-1/ Online ISBN978-981-13-1744-6




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