湖南师范大学化学化工学院

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伏再辉

发布日期:2019年11月26日 15:42浏览次数:


伏再辉

性 别:男

学历:研究生

职称:教授

其他:博士生导师


伏再辉,54岁,硕士,二级教授,有机化学博士生导师。“石化新材料与资源精细利用”国家地方联合工程实验室副主任,“资源精细化与先进材料”湖南高校重点实验室副主任,精细催化合成研究所副所长。湖南省2011协同创新中心“环境友好与资源高效利用化工新技术”首席专家,学校世承人才计划学术骨干。1988年在中科院大连化学物理研究所催化专业硕士毕业。长期从事有机催化、应用催化和工业催化领域的科研与教学工作,在新型催化材料的分子设计、绿色催化氧化、仿酶催化转化等方面硕果累累,一批原创性的研究成果引起国内外同行的高度关注。先后主持完成5项国家自然科学基金和湖南省自然科学基金重点课题、高等学校博士学位点专项科研基金和湖南省教育厅高校重点实验室平台课题,以及与中石化企业的合作研究课题。发明了一类具有催化分子开关结构特征的新一代烯烃环氧化高效的环境友好催化剂,发展了基于分子氧的选择氧化的绿色光催化反应体系和基于生物质炭磺酸催化木质纤维类生物质水解的高效仿酶催化转化体系。提出的“催化剂活性基团的仿生组装”思想被10000个科学难题编委会收录(湖南省仅3人)。在国际重要刊物J. Catal., Adv. Synth. Catal., Green chem., Applied catalysis B-environ., Appl. Catal. A: Gen., J. Mol. Catal. A: Chem., Ind. Eng. Chem. Res., cellulose 等杂志上发表与催化有关的论文40多篇。获2010年度湖南省自然科学三等奖1项。指导1名硕士研究生获湖南省优秀硕士毕业论文、2名博士研究生获国家奖学金,2名硕士研究生获湖南师范大学优秀硕士毕业论文。目前在有机化学、应用化学、工业催化等方向招收硕士研究生,有机化学方向招收博士研究生。

联系方式:fzhhnnu@126.com

主要论著和成果

[1] Chao Zhang, Zengtian Cheng,Zaihui Fu*, et al, Effective transformation of cellulose to 5-Hydroxymethylfurfural catalyzed by fluorine anion-containing ionic liquid modified biochar sulfonic acids in water,Cellulose (2017) 24:95–106

[2] Yongjun Wang, Zaihui Fu*,et al, Weakly distorted 8-quinolinolato iron(III) complexes as effectivecatalysts for oxygenation of organic compounds by hydrogen peroxide,Journal of Molecular Catalysis A: Chemical,2016,411:103-109

[3]Wenfeng Wu,Zaihui Fu*, et al, nBu4N)4W10O32-catalyzed selective oxygenation of cyclohexane by molecular oxygen under visible light irradiation,Appl. Catal. B: Environmental,2015,Vol 164(No1):113-119

[4]Senpei Tang,Wenfeng Wu,Zaihui Fu*, et al, Vanadium-Substituted Tungstophosphoric Acids asEfficient Catalysts for Visible-Light-DrivenOxygenation ofCyclohexane by Dioxygen,ChemCatChem,2015,7:2637-2645

[5] Jialuo She,Zaihui Fu*, et al, Visible light-triggered vanadium-substituted molybdo phosphoricacids to catalyze liquid phase oxygenation of cyclohexane to KA oil bynitrous oxide,Applied Catalysis B: Environmental,2016,182:392-404

[6] Shuai Zou,Zaihui Fu*, et al, Mild, one-step hydrothermal synthesis of carbon- coated CdS nanoparticles with improved photocatalytic activity and stability,Chinese Journal of Catalysis 36 (2015) 1077–1085

[7] Chao. Zhang, Zaihui Fu*, et al., Biochar sulfonic acid immobilized chlorozincate ionic liquid: an efficiently biomimetic and reusable catalyst for hydrolysis of cellulose and bamboo under microwave irradiation,Cellulose, (2014) 21:1227–1237

[8] Wenfeng Wu,Zaihui Fu*, et al., Light-triggered oxy-chlorination of cyclohexane by metal chlorides,Appl. Catal. A: Gen., Vol4697, p 483-489,2014.

[9] Yongjun Wang,Zaihui Fu*, et al., 8-Quinolinolato iron(III)-catalyzed oxygenation of cyclohexane with hydrogen peroxide under heating or visible light irradiation,J. Mol. Catal. A: Chem., Vol 383-384,p 46-52,2014.

[10] Chao. Zhang, Zaihui Fu*, et al., Chlorocuprate Ionic Liquid Functionalized Biochar Sulfonic Acid as an Efficiently Biomimetic Catalyst for Direct Hydrolysis of Bamboo under Microwave Irradiation ,Ind. Eng. Chem. Res., Vol52, p 11537−11543,2013.

[11] Wenfeng Wu, Xianglin. He,Zaihui Fu*, et al., Metal chlorides-catalyzed selective oxidation of cyclohexane by molecular oxygen under visible light irradiation, J. Catal., Vol 286,p 6-12,2012.

[12] Chao. Zhang, Zaihui Fu*, et al., Ionic liquid- functionalized biochar sulfonic acid as a biomimetic catalyst forhydrolysis of cellulose and bamboo under microwave irradiation,Green Chem., No 14,p1928-1934,2012.

[13] Youyu Wu, Chao. Zhang, Yachun Liu*,Zaihui Fu*, et al., Biomass sulfonic acids (BC-SO3H)-catalyzed hydrolysis of bamboo under microwave irradiation, Bioresources, Vol 7, p 5950-5959,2012.

[14]秦金伟,伏再辉*,等, N-羟基邻苯二甲酰亚胺与 8-羟基喹啉氧钒 (IV)配合物协同催化分子氧氧化乙苯,催化学报,Vol 32, No8,p 1342-1348,2011.

[15] Youyu Wu,Zaihui Fu*, et al., Microwave-assisted hydrolysis of crystalline cellulose catalyzed by biomass char sulfonic acids,Green Chem.,No 12, p696-700,.2010.

[16] Chunli Lu,Zaihui Fu*, et al., A moderate and efficient method for oxidation of ethylbenzene with hydrogen peroxide catalyzed by 8-quinolinolato manganese(III) complexes,J. Mol. Catal. A: Chem., Vol331,p 106-113,2010.

[17] Fenglan Liu,Zaihui Fu*, et al., A simple and environmentally benign method for sulfoxidation of Sulfides with hydrogen peroxide, Ind. Eng. Chem. Res., Vol 49,p 2533-2536,2010.

[18] Lu Chun-Li,Fu Zai-Hui*, et al., Selective Oxidation of Ethylbenzene with Hydrogen Peroxide Catalyzed by 5,7-Dibromo-8-quinolinolato Manganese Complexes,Acta Physico-Chimica Sinica, Vol26,No 10,p 2705-2710,2010.

[19] Zhengpei Ye,Zaihui Fu*, et al., Selective oxidations of alcohols with hydrogen peroxide catalyzed by changeable hexadentate 8-quinolinolato manganese (III) complexes,J. Catal.,Vol 261,p110-115,2009.

[20] Fang Xie, Zaihui Fu*, et al., Thioanisole oxidation with hydrogen peroxide catalyzed by hexadentate 8-quinolinolato manganese (III) complexes,J. Mol. Catal. A: Chem., Vol307,p93-97,2009.

[21] Fang Xie,Zaihui Fu*, et al., Catalytic Oxidative Removal of Demethysulfoxide by Hexadentate 8-Quinolinolato Manganese(III) Complexes”,Chin. J. Catal., Vol 30,No 10,p981 -985,2009.

[22] Seng. Zhong, Yueming Tan,Zaihui Fu*,et al., A highly efficient epoxidation method of olefins with hydrogen peroxide catalyzed by changeable hexadentate 8-quinolinolato manganese(III) complexes,J. Catal., Vol256,p 154-158,2008.

[23] Seng. Zhong,Zaihui Fu*, et al., 5-chloro-7-iodo-8-quinolinolato manganese(III) with the feature of pH-regulated molecular switches as a highly-efficient catalyst for epoxidation of olefins with hydrogen peroxide,Advanced Synthesis and Catalysis,Vol 350,p 802-806,2008.

[24] Zaihui Fu et al., Epoxidation of cyclohexene with molecular oxygen by electrolysis combined with chemical catalysis,J IRAN CHEM SOC., DOI 10.1007/s13738-014-0445-3,2014.

[25]伏再辉,催化剂活性基团的仿生组装,10000个科学难题化学卷,科学出版社, p 157-159,约4500字,2010.

[26]伏再辉,尹笃林,衷晟,肖毅,精细化学产品合成中的环境友好型催化剂设计,获2010年湖南省自然科学三等奖(证书号:20102035-Z3-032-R02),2010.

[27]伏再辉,衷晟,熊东路,谢芳,尹笃林, 8-羟基喹啉衍生物的锰催化剂及其在烯烃环氧化中的应用,中国专利,专利号:ZL 2006 1 0136989.4. 2010.

[28]伏再辉,张超,尹笃林,刘亚纯,一种在纯水中碳水化合物有效转化为5-羟甲基糠醛的方法,申请号:201410000266.6.

[29]刘亚纯,伏再辉,张超,尹笃林,一种生物质碳微/纳米球的低温水热制备方法,申请号:201310576127.3.

[30]伏再辉、吴文锋、尹笃林、刘亚纯、张超,一种可见光激发十聚钨酸盐催化有机物选择氧化的有效体系,中国,201410245885.1

[31]伏再辉、吴文锋、汤森培、尹笃林、刘亚纯、张超、邹帅,一种盐酸促进PWV杂多酸光催化环己烷氧化制KA油的有效体系,中国,201410245869.2。

[32]伏再辉、佘家骆,汤森培,一种利用N2O选择氧化碳氢化合物的有效光催化体系,中国,201510352327X

[33]伏再辉、向超、张超、刘亚纯,一种利用微波-CuO处理造纸废液制备木素酚醛树脂胶黏剂的方法,中国,201510352326.5

[34]伏再辉、冯瑶、张超、刘亚纯,一种硅胶柱撑介孔生物质碳固体磺酸的方法,中国,201710017071.6

[35]伏再辉、张荣、张超、刘亚纯,一种超高磺酸密度生物质碳固体酸的制备方法,201710018002.9

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